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The beauty of Luster Grey is the way in which it breaks up the traditional single colour fabrics with dashes of white. It gives the whole blind a larger than life quality that lets the light flow around your room without saturating the existing colours.
Introducing other finely detailed finishes would be an inspired choice if you want to continue the theme around the room. Look to the natural world for inspiration by focusing on the huge variety of wood grains that you can introduce with your furniture and flooring.